将三种不同的有机金属依次插入到含有 PNA 骨架的多功能砌块中。
Sequential insertion of three different organometallics into a versatile building block containing a PNA backbone.
机构信息
Lehrstuhl für Anorganische Chemie I, Fakultät für Chemie und Biochemie, Ruhr-Universität Bochum, Gebäude NC 3 Nord, Universitätsstr. 150, 44801, Bochum, Germany.
出版信息
Dalton Trans. 2010 Jun 28;39(24):5617-9. doi: 10.1039/c003598j. Epub 2010 May 19.
DOI:10.1039/c003598j
PMID:20485811
Abstract
In the view of developing a synthetic route for the controlled insertion of distinct organometallic moieties into peptide nucleic acid (PNA) oligomers, a proof-of-principle study of the chemoselective insertion of three different organometallics into a building block containing both a PNA backbone and an alkyne side-chain is presented in this study.
摘要
在开发一种将不同的有机金属片段可控地插入肽核酸（PNA）寡聚物的合成路线的过程中，本研究提出了一个原理性研究，即通过化学选择性地将三种不同的有机金属插入含有 PNA 主链和炔烃侧链的构建块中。
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