Department of Material Science, The Silesian University of Technology, Poland.
J Microsc. 2010 Mar;237(3):450-5. doi: 10.1111/j.1365-2818.2009.03290.x.
This study was done on the IN-738 type alloy with thermal barrier coatings. On the basic surface of the NiCoCrAlY superalloy, VPS-sprayed powder was applied as the bond-coat. In addition, ZrO(2)x 8%Y(2)O(3) powder was used for a deposition outside the top surface of a ceramic layer by the APS method. Appropriate control of the spraying process parameters permitted to obtain a gradient of porosity on the thickness of the ceramic coating. Then a static oxidation test at 1100 degrees C and for 1100 h was performed. The basic conclusions of that testing showed that main degradation modes of the gradient thermal barrier coating system were connected with formation of porous NiAl(2)O(4) oxides in the thermally grown oxide area and, consequently, formation of micro-cracks, delamination of a ceramic layer and final spallation of a ceramic top-coat.
本研究针对带热障涂层的 IN-738 型合金。在 NiCoCrAlY 超合金的基础表面上,采用 VPS 喷涂粉末作为粘结层。此外,还采用 APS 方法在陶瓷层的顶面外部沉积 ZrO(2)x 8%Y(2)O(3)粉末。通过适当控制喷涂工艺参数,可以在陶瓷涂层厚度上获得孔隙率梯度。然后在 1100°C 下进行 1100 h 的静态氧化测试。该测试的基本结论表明,梯度热障涂层系统的主要降解模式与热生长氧化物区域中多孔 NiAl(2)O(4)氧化物的形成有关,从而导致微裂纹的形成、陶瓷层的分层和最终陶瓷顶层的剥落。