State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing 100085, China.
Chemosphere. 2010 Aug;80(9):998-1005. doi: 10.1016/j.chemosphere.2010.05.036. Epub 2010 Jun 16.
A number of approaches have been proposed for screening level ecological risk assessment. In this paper, we first established a mass spectrum library including 50 phenols using retention time locking (RTL) technology and deconvolution reporting software (DRS). Distribution of phenols in surface water of the Taihu Lake was screened. Among the 22 identified phenols, 14 phenols were quantified. The concentrations of total phenols ranged 675.2-3346.1 ng L(-1). The distributions of ecological effect quotients (EEQs) of 14 phenols were characterized in terms of the exposure concentration distributions (ECDs) and species sensitivity distributions (SSDs). Those phenols with EEQs exceeding the threshold proposed by Water Environment Research Foundation of Alexandria were selected as priorities. As a result, 2-nitrophenol (2-NP), p-chloro-m-xylenol (PCMX) and pyrocatechol were determined as potential ecological risk stressors in surface water of the Taihu Lake. Results of the present study suggested that the proposed approach is feasible for the screening level ecological risk assessment.
已经提出了许多方法来进行筛选水平的生态风险评估。在本文中,我们首先使用保留时间锁定(RTL)技术和去卷积报告软件(DRS)建立了一个包含 50 种酚类物质的质谱库。筛选了太湖地表水的酚类物质分布。在鉴定出的 22 种酚类物质中,有 14 种被定量。总酚的浓度范围为 675.2-3346.1ng/L。根据暴露浓度分布(ECD)和物种敏感性分布(SSD),对 14 种酚类物质的生态效应系数(EEQ)分布进行了特征描述。那些 EEQ 超过亚历山大水环境研究基金会提出的阈值的酚类物质被选为优先物质。结果表明,2-硝基苯酚(2-NP)、对氯间二甲苯酚(PCMX)和邻苯二酚被确定为太湖地表水的潜在生态风险胁迫物。本研究结果表明,所提出的方法对于筛选水平的生态风险评估是可行的。