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pH 值对基于紫外线的高级氧化技术的影响——1,4-二恶烷降解。

The effect of pH on UV-based advanced oxidation technologies--1,4-dioxane degradation.

机构信息

ARC Centre of Excellence for Functional Nanomaterials, School of Chemical Sciences and Engineering, The University of New South Wales, NSW 2052, Australia.

出版信息

J Hazard Mater. 2010 Oct 15;182(1-3):75-9. doi: 10.1016/j.jhazmat.2010.06.001. Epub 2010 Jun 8.

Abstract

1,4-Dioxane, is a synthetic organic compound used widely throughout industry as a solvent. 1,4-Dioxane causes liver damage and kidney failure and has been shown to be carcinogenic to animals, and is a potential carcinogen to humans. Its recalcitrant nature means that conventional water treatment methods are ineffective in removing it from water. A class of technologies called advanced oxidation technologies has been shown to completely mineralise 1,4-dioxane. In this study the effects of pH on TiO(2) photocatalysis reactor systems were investigated. pH was found to significantly affect the efficiencies of these processes with neutral pH conditions the most effective.

摘要

1,4-二恶烷是一种广泛应用于工业生产的合成有机化合物,可用作溶剂。1,4-二恶烷会造成肝脏损伤和肾衰竭,并且对动物具有致癌性,对人类而言也可能是一种潜在的致癌物质。由于其稳定性,传统的水处理方法无法有效去除水中的 1,4-二恶烷。一类被称为高级氧化技术的技术已被证明可完全将 1,4-二恶烷矿化。在这项研究中,考察了 pH 值对 TiO(2)光催化反应器系统的影响。结果发现,pH 值会显著影响这些过程的效率,其中中性 pH 值条件的效果最佳。

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