Chapin Brette M, Hughs Lauren D, Golen James A, Rheingold Arnold L, Johnson Adam R
Department of Chemistry, Harvey Mudd College, 301 Platt Boulevard, Claremont, CA 91711, USA.
Acta Crystallogr C. 2010 Jul;66(Pt 7):m191-3. doi: 10.1107/S0108270110023176. Epub 2010 Jun 24.
The title complex, [Ti(C(5)H(5))(C(2)H(6)N)(2)Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti-->cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long-range contacts between Ti-Cl and cyclopentadienyl H-C groups give rise to geometric ordering in the extended solid.
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