具有改进的光物理性质和集成功能化的异双（三齿）钌（II）聚吡啶配合物。
A heteroleptic bis(tridentate)ruthenium(II) polypyridine complex with improved photophysical properties and integrated functionalizability.
机构信息
Institute of Inorganic Chemistry and Analytical Chemistry, Johannes Gutenberg-University of Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.
出版信息
Inorg Chem. 2010 Aug 2;49(15):7052-6. doi: 10.1021/ic1007236.
The synthesis and photophysical properties of a ruthenium(II) complex bearing an electron-accepting 2,2';6',2''-terpyridine ligand and an electron-donating N,N'-dimethyl-N,N'-dipyridin-2-ylpyridine-2,6-diamine (ddpd) ligand are presented. The heteroleptic complex is easily prepared isomerically pure and features intense low-energy metal-to-ligand charge-transfer (MLCT) absorption bands and intense room temperature (3)MLCT emission with a long (3)MLCT lifetime. The favorable photophysical properties are due to the strong ligand field imposed by the ddpd ligand.
本文介绍了一种含有电子受体 2,2';6',2''-三联吡啶配体和电子给体 N,N'-二甲基-N,N'-二吡啶-2-基-2,6-二吡啶胺（ddpd）配体的钌（II）配合物的合成及光物理性质。该杂配配合物易于制备，且具有异构体纯的特点，表现出强的低能量金属-配体电荷转移（MLCT）吸收带和强的室温（3）MLCT 发射，且（3）MLCT 寿命长。有利的光物理性质归因于 ddpd 配体所施加的强配体场。
Zotero 插件