School of Chemical Engineering, Nanjing University of Science & Technology, 200 Xiao Ling Wei, Nanjing 210094, China.
Water Sci Technol. 2010;62(2):330-9. doi: 10.2166/wst.2010.292.
The enhanced coagulation of algae-rich raw water from Lake Taihu in summer was studied by use of composite coagulants. The composite coagulants were composed of polyaluminum chloride (PAC) and polydimethyldiallylammonium chloride (PDM) with various intrinsic viscosity values (0.55-3.99 dL/g) and different mass percentages (5-20%) in the formulation. For raw water with temperature of 28-29 degrees C and algae content of 3.60x10(4)-3.70x10(4) cells/ml, the algae-removal rates of 89.0% and 89.3-93.1% could be realized by using PAC and PAC/PDM (0.55/5%-3.99/20%) with dosages of 8.37 mg/L and 5.93-3.58 mg/L, respectively, when 2 NTU residual turbidity of treated water after sedimentation was required. Compared with using PAC only, the removal rate of CODMn using PAC/PDM increased at least 4.4% when the dosage was 8 mg/L, and increased at least 5.0% when the dosage was 10 mg/L. The composite coagulants could still function well when raw water quality deteriorated and algae content reached 8.00x10(4) cells/ml. The enhanced coagulation efficiency of PAC/PDM (0.55/5%) could be better than that of PAC combined with prechlorination process when the same dosages are used.
采用复合混凝剂对夏季富藻太湖水进行强化混凝研究。复合混凝剂由聚合氯化铝(PAC)和不同特性黏数(0.55-3.99 dL/g)和不同质量百分比(5-20%)的聚二甲基二烯丙基氯化铵(PDM)组成。对于温度为 28-29°C,藻类含量为 3.60x10(4)-3.70x10(4) 个细胞/ml 的原水,当需要沉淀后处理水的 2 NTU 残余浊度时,分别使用 8.37 mg/L 和 5.93-3.58 mg/L 的 PAC 和 PAC/PDM(0.55/5%-3.99/20%),可以实现 89.0%和 89.3-93.1%的藻类去除率。与单独使用 PAC 相比,当剂量为 8mg/L 时,使用 PAC/PDM 可以至少提高 4.4%的 CODMn 去除率,当剂量为 10mg/L 时,至少提高 5.0%的 CODMn 去除率。当原水水质恶化,藻类含量达到 8.00x10(4) 个细胞/ml 时,复合混凝剂仍能很好地发挥作用。当使用相同剂量时,PAC/PDM(0.55/5%)的强化混凝效率可能优于 PAC 与预氯化工艺的结合。