Laboratory of Molecular Catalysis, Universidade Federal do Rio Grande do Sul, Avenida Bento Gonçalves 9500, 91501-970 Porto Alegre/RS, Brazil.
Molecules. 2010 May 12;15(5):3441-61. doi: 10.3390/molecules15053441.
A brief summary of selected pioneering and mechanistic contributions in the field of carbon-carbon cross-coupling reactions with palladium nanoparticles (Pd-NPs) in ionic liquids (ILs) is presented. Five exemplary model systems using the Pd-NPs/ILs approach are presented: Heck, Suzuki, Stille, Sonogashira and Ullmann reactions which all have in common the use of ionic liquids as reaction media and the use of palladium nanoparticles as reservoir for the catalytically active palladium species.
本文简要综述了钯纳米粒子（Pd-NPs）在离子液体（ILs）中碳-碳交叉偶联反应领域的开创性和机理贡献。本文提出了使用 Pd-NPs/ILs 方法的五个典型模型体系：Heck、Suzuki、Stille、Sonogashira 和 Ullmann 反应，它们的共同点是使用离子液体作为反应介质，使用钯纳米粒子作为催化活性钯物种的储库。
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