Microscopic model of carbonaceous nanoporous molecular sieves--anomalous transport in molecularly confined spaces.

To model the equilibrium and transport properties of carbonaceous molecular sieves (CMS) (i.e., carbon membranes, coals, activated carbons with ink-bottle pore geometry, etc.) the new microscopic turbostratic carbon pore model (TCPM) is developed. Analysis of experimental Gibbs excess of methane adsorption on Shirasagi CMS 3K-161 at 298 K indicates that investigated CMS is structurally a heterogonous material (i.e., it is composed of slit-shaped and turbostratic carbon nanopores of different sizes). The predicted absolute methane isotherm, total pore volume of 0.22 cm(3) g(-1), enthalpy of methane adsorption of 17.5-18.6 kJ mol(-1) on Shirasagi CMS 3K-161 at 298 K are in good agreement with existing experimental and theoretical data. Applying TCPM, we model the equilibrium and kinetic separation of hydrogen and methane mixtures adsorbed in CMS turbostratic carbon nanopores at infinite dilution and 194.7, 293.2, 313.2, 423.2, and 573.2 K. We found that near ambient temperatures one can reach equilibrium selectivity of methane over hydrogen (CH(4)/H(2)) of 10(2) in the turbostratic carbon nanopores having effective cage sizes of ≈5 Å. Lowering an operating temperature down to the dry ice one increases the equilibrium CH(4)/H(2) selectivity in these nanopores up to 10(3). The kinetic selectivity of hydrogen over several investigated fluids, including: methane, argon, xenon, nitrogen, and carbon dioxide at studied operating conditions does not depend on the size of the carbon nanopore cage. This simply means that the kinetic separation factor is controlled by the size of the carbon nanopore constriction. Taking this into account, we predicted the effective size of the carbon nanopore constriction of real CMS from the experimentally measured kinetic H(2)/CH(4) selectivities at infinite dilution. The high kinetic H(2)/CH(4) selectivity of 10(2)-10(3) corresponds to the effective size of the carbon nanopore constriction of ≤2.958 Å (i.e., lower or equal to the collision diameter of hydrogen molecule). However, decreasing/increasing of the effective size of the carbon nanopore constriction by ≈0.1-0.2 Å exponentially increases/decreases kinetic H(2)/CH(4) separation factor. Finally, we showed that the efficiency of kinetic separation at 298 K and infinite dilution depends on the σ(H(2))/σ(X) and not only on σ(H(2)) (where σ denotes the collision diameter of hydrogen and the mentioned above fluids, respectively).