Department of Physics and Astronomy, Complexity Science Group, University of Calgary, Calgary, Alberta T2N 1N4, Canada.
J Chem Phys. 2010 Jul 28;133(4):044909. doi: 10.1063/1.3464493.
Under a change of conditions, spiral waves in oscillatory reaction-diffusion media can become unstable and give rise to a multitude of emergent patterns. For example, in bounded domains spiral waves can undergo a resonant Hopf bifurcation leading to period-2 spirals which emit wave trains with doubled wavelength and temporal period and have a characteristic synchronization defect line. Here, we analyze the emergent patterns due to nonresonant Hopf bifurcations in the local dynamics giving rise to quasiperiodicity as reported in systems such as the peroxidase-oxidase and the Belousov-Zhabotinsky reaction. For a conceptual model of the peroxidase-oxidase reaction in a spatially extended medium, we find numerically that the additional frequency leads to defect-mediated turbulence. This proves that defect-mediated turbulence can indeed exist in media where the underlying local dynamics is quasiperiodic. While many statistical features of this turbulent dynamics are similar to those observed for other systems, we show that there are clear differences if higher-order statistics are considered. In particular, we find that the space-time dynamics of the topological defects as characterized by the statistics of defect loops is closely related to the underlying local dynamics.
在条件变化下,震荡反应扩散介质中的螺旋波可能变得不稳定,并产生多种突发模式。例如,在有界区域中,螺旋波可能经历共振 Hopf 分岔,导致周期为 2 的螺旋,其发射具有两倍波长和时间周期的波列,并具有特征性的同步缺陷线。在这里,我们分析了在局部动力学中导致非共振 Hopf 分岔的突发模式,从而产生了如过氧化物酶-氧化酶和 Belousov-Zhabotinsky 反应等系统中所报道的准周期性。对于过氧化物酶-氧化酶反应在空间扩展介质中的概念模型,我们通过数值发现,附加频率导致缺陷介导的湍流。这证明了在局部动力学为准周期性的介质中确实可以存在缺陷介导的湍流。虽然这种湍流动力学的许多统计特征与其他系统观察到的相似,但我们表明,如果考虑高阶统计量,就会存在明显的差异。特别是,我们发现拓扑缺陷的时空动力学,如缺陷环的统计所描述的,与基础局部动力学密切相关。