构建新型 Zn-Ni 三核席夫碱和 Ni2+化学传感器。
Construction of a novel Zn-Ni trinuclear Schiff base and a Ni2+ chemosensor.
机构信息
School of Chemistry and Environment, Key Lab of Technology on Electrochemical Energy Storage and Power Generation in Guangdong Universities, Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), South China Normal University, Guangzhou 510006, People's Republic of China.
出版信息
Inorg Chem. 2010 Aug 16;49(16):7241-3. doi: 10.1021/ic101036m.
A novel Zn-Ni heterotrinuclear Schiff base compound bearing acacen(2-) moieties was constructed through the selective assembly of a chemosensor Schiff base zinc compound with a Ni(2+) ion. Its crystal structure not only clearly explains the binding mode between the chemosensor molecule and the detected metal ion but also represents the first trinuclear complex based on a symmetric acacen(2-) base Schiff base.
一个新型的 Zn-Ni 异核三核席夫碱化合物，带有 acacen(2-) 部分，是通过化学传感器席夫碱锌化合物与 Ni(2+) 离子的选择性组装而构建的。它的晶体结构不仅清楚地解释了化学传感器分子与被检测金属离子的结合模式，而且还代表了第一个基于对称 acacen(2-) 基席夫碱的三核配合物。
Zotero 插件