炔基金属锆酸盐与烯丙基溴的反应性：β-烯丙基-锆杂环戊二烯的选择性形成。
Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes.
机构信息
Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
出版信息
Chem Commun (Camb). 2010 Nov 7;46(41):7801-3. doi: 10.1039/c0cc02997a. Epub 2010 Sep 20.
PMID:20856945
Abstract
Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.
摘要
炔基金属锆酸盐与烯丙基溴反应，在独特的反应位点高选择性地得到了β-烯丙基-锆杂环戊二烯。
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