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[冬季室内气态空气污染物的特征]

[Characteristics of indoor gaseous air pollutants in winter].

作者信息

Yamada Tomomi, Ohta Mayu, Ucmiyami Shigehisa, Inaba Yohei, Goto Sumio, Kunugita Naoki

机构信息

Department of Environmental Health, National Institute of Public Health, Wako-shi, Saitama 351-0197, Japan.

出版信息

J UOEH. 2010 Sep 1;32(3):245-55. doi: 10.7888/juoeh.32.245.

Abstract

There are many gaseous air pollutants found in indoor air. It is very important to precisely measure the concentration of these compounds in order to evaluate the risk to human health and to reduce their concentrations. A diffusive sampling device is suitable for measurement of indoor air, because these are small, light, and can be used without a power supply for the pump. In this study, representative gaseous air pollutants in winter indoor and outdoor air were measured using diffusive sampling devices. Furthermore, the relationship between gaseous air pollutants, secondary formation mechanism, and the outbreak source were examined. The indoor concentrations of aldehydes, nitrogen dioxide and ammonia were higher than outdoor concentrations. By contrast, indoor concentrations of ozone were lower than outdoor concentrations. The indoor concentrations of nitrogen dioxide in 43% houses exceeded the maximum limit stated by environmental law (60 ppb). It was suggested that the main emission sources of nitrogen dioxide are kerosene and gas stoves. In addition, it was suggested that carbonyl compounds are formed by interactions between volatile organic compounds (VOCs) and ozone from outdoor air. Formic acid was estimated to be formed by the oxidation of formaldehyde with ozone, because a positive correlation between formaldehyde and formic acid, and an inverse correlation between formaldehyde and ozone, were observed in indoor air.

摘要

室内空气中存在多种气态空气污染物。精确测量这些化合物的浓度对于评估对人类健康的风险以及降低其浓度非常重要。扩散采样装置适用于室内空气测量,因为它们体积小、重量轻,且无需泵的电源即可使用。在本研究中,使用扩散采样装置测量了冬季室内和室外空气中具有代表性的气态空气污染物。此外,还研究了气态空气污染物、二次形成机制与爆发源之间的关系。室内醛类、二氧化氮和氨的浓度高于室外浓度。相比之下,室内臭氧浓度低于室外浓度。43%房屋中的室内二氧化氮浓度超过了环境法规定的最大限值(60 ppb)。据推测,二氧化氮的主要排放源是煤油炉和燃气炉。此外,据推测羰基化合物是由挥发性有机化合物(VOCs)与室外空气中的臭氧相互作用形成的。在室内空气中观察到甲醛与甲酸呈正相关,甲醛与臭氧呈负相关,因此估计甲酸是由甲醛与臭氧氧化形成的。

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