Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-UM2-ENSCM-UM1, CC 15003, Université Montpellier 2, Place Eugène Bataillon, 34095 Montpellier cedex 5, France.
J Hazard Mater. 2011 Jan 15;185(1):236-41. doi: 10.1016/j.jhazmat.2010.09.023. Epub 2010 Sep 17.
Foam glass manufacture is a promising mode for re-using cathode ray tube (CRT) glasses. Nevertheless, because CRTs employ glasses containing heavy metals such as lead, barium and strontium, the leaching behaviour of foam glasses fabricated from CRTs must be understood. Using the AFNOR X 31-210 leaching assessment procedure, the degree of element inertization in foam glasses synthesized from waste CRT glasses (funnel and panel glasses, containing lead and barium/strontium respectively) were determined. The amount of leached lead from foam glasses prepared from funnel glass depends on the nature and concentration of the reducing agent. The effects of the reducing agents on the generation of cellular structure in the fabrication of foam glass were studied. The fraction of lead released from foam glass was less than those extracted from funnel glass and was lower than the statutory limit. Leached concentrations of barium and strontium were found to be approximately constant in various tests and were also below regulatory limits.
泡沫玻璃制造是一种很有前途的再利用阴极射线管(CRT)玻璃的方式。然而,由于 CRT 采用了含有重金属如铅、钡和锶的玻璃,因此必须了解由 CRT 制造的泡沫玻璃的浸出行为。使用 AFNOR X 31-210 浸出评估程序,确定了由废 CRT 玻璃(分别含有铅和钡/锶的漏斗和面板玻璃)合成的泡沫玻璃中元素惰性化的程度。由漏斗玻璃制备的泡沫玻璃中浸出的铅量取决于还原剂的性质和浓度。研究了还原剂对泡沫玻璃制造中蜂窝结构生成的影响。从泡沫玻璃中释放出的铅的比例低于从漏斗玻璃中提取的铅,并且低于法定限值。在各种测试中,钡和锶的浸出浓度发现大致保持不变,也低于监管限值。