Department of Building Science, Tsinghua University, Beijing, China.
Indoor Air. 2010 Dec;20(6):523-9. doi: 10.1111/j.1600-0668.2010.00675.x.
The initial emittable concentration of volatile organic compounds (VOC) is a key parameter not only in evaluating the 'green' degree of building materials but also in modeling their emission characteristics. Although the impact of temperature on initial emittable concentration is important, it has not been reported in the literature. Using the multi-emission/flush regression method we developed, the impact of temperature on the initial emittable concentration of formaldehyde in medium density board has been experimentally studied. It is observed that the initial emittable concentration increases significantly with increasing temperature. When the temperature rises by 25.4°C, it increases by about 507%. However, the initial emittable concentration at room temperature is far less than the value measured by the perforator method recommended by the Chinese National Standard GB/T 17657-1999, which measures the total concentration of formaldehyde in medium density board. This means most of formaldehyde in the building material cannot emit out at room temperature. The results will be very helpful in estimating the emission characteristics of building materials at different temperatures as well as for developing green building materials.
Knowledge of initial emittable concentration is important for VOC emission prediction. According to our experimental study, the initial emittable concentration is heavily dependent on temperature, and this factor should be considered in dealing with heating or cooling process of building materials. The significant difference between the initial emittable concentration and total concentration suggests that the total concentration seems not appropriate for judging the pollution level of building materials.
挥发性有机化合物(VOC)的初始可散发浓度不仅是评估建筑材料“绿色”程度的关键参数,也是建模其排放特性的关键参数。尽管温度对初始可散发浓度的影响很重要,但文献中并未报道过。使用我们开发的多排放/冲洗回归方法,实验研究了温度对中密度板中甲醛初始可散发浓度的影响。结果表明,初始可散发浓度随温度的升高而显著增加。当温度升高 25.4°C 时,其增加约 507%。然而,在室温下的初始可散发浓度远低于中国国家标准 GB/T 17657-1999 推荐的穿孔器法测量的中密度板中甲醛的总浓度值。这意味着建筑材料中大部分甲醛在室温下无法散发出来。研究结果对于预测不同温度下建筑材料的排放特性以及开发绿色建筑材料非常有帮助。
初始可散发浓度的知识对于 VOC 排放预测很重要。根据我们的实验研究,初始可散发浓度严重依赖于温度,在处理建筑材料的加热或冷却过程时应考虑这一因素。初始可散发浓度与总浓度之间的显著差异表明,总浓度似乎不适合判断建筑材料的污染水平。