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用滤纸从水环境中去除碳纳米管。

Removal of carbon nanotubes from aqueous environment with filter paper.

机构信息

Institute of Nanochemistry and Nanobiology, Shanghai University, China.

出版信息

Chemosphere. 2011 Jan;82(4):621-6. doi: 10.1016/j.chemosphere.2010.10.048. Epub 2010 Nov 10.

Abstract

The potential health and environmental hazards of carbon nanotubes (CNTs) have been a concerned issue. However, in contrast to the wide recognition of the toxicity of CNTs, little attention has been paid to the decontamination/remediation of CNT pollution. In this study, we report that CNTs can be removed from aqueous environment. In the presence of Ca²(+), CNTs aggregate quickly to micron size and then enable easy and effective removal via normal filtration. After filtration, CNT suspension becomes colorless with the remnant CNT concentration less than 0.5 μg mL⁻¹, a safe dose based on the published data. The filtration approach also works well in the presence of typical surfactant and dissolved organic matter. The removal efficiency is Ca²(+) concentration-dependent and regulated by the initial pH value and ionic strength. Our study is helpful for future decontamination of CNTs from aqueous environment.

摘要

碳纳米管 (CNTs) 的潜在健康和环境危害一直是人们关注的问题。然而,与 CNTs 毒性被广泛认可形成鲜明对比的是,人们对 CNT 污染的净化/修复问题关注甚少。在这项研究中,我们报告 CNTs 可以从水相环境中去除。在 Ca²(+) 存在的情况下,CNTs 迅速聚集到微米级大小,然后通过常规过滤实现方便且有效的去除。过滤后,CNT 悬浮液变为无色,残余 CNT 浓度低于 0.5 μg mL⁻¹,这是基于已发表数据的安全剂量。该过滤方法在存在典型表面活性剂和溶解有机物的情况下也能很好地发挥作用。去除效率与 Ca²(+) 浓度有关,并受初始 pH 值和离子强度的调节。我们的研究有助于未来从水相环境中去除 CNTs。

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