将[2]轮烷连接起来，制造出一种新型的金属有机轮烷框架。
Linking [2]rotaxane wheels to create a new type of metal organic rotaxane framework.
机构信息
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, Canada.
出版信息
Chem Commun (Camb). 2011 Jan 21;47(3):896-8. doi: 10.1039/c0cc04139d. Epub 2010 Nov 12.
PMID:21072427
Abstract
Three new [2]rotaxanes with aromatic nitrogen donors appended to the crown ether wheel have been synthesized and used as ligands to coordinate Cd(II) ions. One of these yields a new type of 2-periodic, metal organic rotaxane framework in which the wheel rather than the axle is used to link the metal nodes.
摘要
合成了三个带有芳族氮供体的新型[2]轮烷，并将其用作配体以配位 Cd(II) 离子。其中一种生成了一种新型的 2 周期金属有机轮烷骨架，其中轮烷而不是轴用于连接金属节点。
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