C72Cl4：具有有利的五元环相邻结构的原始富勒烯。
C72Cl4: a pristine fullerene with favorable pentagon-adjacent structure.
机构信息
State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
出版信息
J Am Chem Soc. 2010 Dec 8;132(48):17102-4. doi: 10.1021/ja108860y. Epub 2010 Nov 12.
A long-sought empty non-IPR fullerene, (#11188)C72, which is more stable than the sole IPR isomer in the fullerene[72] family, has been retrieved and crystallographically characterized as (#11188)C72Cl4. Mass spectrometric data support the facile dechlorination of (#11188)C72Cl4 and, in turn, the possible stability of pristine (#11188)C72.
一种长期以来备受期待的空非 IPR 富勒烯 (#11188)C72，其稳定性超过富勒烯[72]家族中唯一的 IPR 异构体，已被回收并通过晶体学进行了表征，结果为 (#11188)C72Cl4。质谱数据支持 (#11188)C72Cl4 的易脱氯，进而支持原始 (#11188)C72 的可能稳定性。
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