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碳包覆的 SnO2 纳米管:模板参与合成及其在锂离子电池中的应用。

Carbon-coated SnO2 nanotubes: template-engaged synthesis and their application in lithium-ion batteries.

机构信息

State Key Lab of Silicon Materials and Department of Materials Science and Engineering, Zhejiang University, Hangzhou, 310027, PR China.

出版信息

Nanoscale. 2011 Feb;3(2):746-50. doi: 10.1039/c0nr00716a. Epub 2010 Nov 29.

Abstract

This paper reports the synthesis of carbon-coated SnO2 (SnO2-C) nanotubes through a simple glucose hydrothermal and subsequent carbonization approach by using Sn nanorods as sacrificial templates. The as-synthesized SnO2-C nanotubes have been applied as anode materials for lithium-ion batteries, which exhibit improved cyclic performance compared to pure SnO2 nanotubes. The hollow nanostructure, together with the carbon matrix which has good buffering effect and high electronic conductivity, can be responsible for the improved cyclic performance.

摘要

本文通过葡萄糖水热法和以 Sn 纳米棒为牺牲模板的后续碳化处理,合成了碳包覆的 SnO2(SnO2-C)纳米管。所合成的 SnO2-C 纳米管被用作锂离子电池的阳极材料,与纯 SnO2 纳米管相比,其循环性能得到了改善。空心纳米结构以及具有良好缓冲作用和高导电性的碳基质可以解释其循环性能的提高。

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