Claver Irakoze Pierre, Zhang Haihua, Li Qin, Zhu Kexue, Zhou Huiming
State Key Laboratory of Food Science and Technology, Jiangnan University, Lihu Road 1800, Wuxi 214122, China; E-Mails:
Int J Mol Sci. 2010 Aug 16;11(8):3002-15. doi: 10.3390/ijms11083002.
Starches were isolated from soaked and malted sorghum and studied to understand their physicochemical and functional properties. The swelling power (SP) and the water solubility index (WSI) of both starches were nearly similar at temperatures below 50 °C, but at more than 50 °C, the starch isolated from malted sorghum showed lower SP and high WSI than those isolated from raw and soaked sorghum. The pasting properties of starches determined by rapid visco-analyzer (RVA) showed that malted sorghum starch had a lower viscosity peak value (86 BU/RVU) than raw sorghum starch (454 BU/RVU). For both sorghum, X-ray diffractograms exhibited an A-type diffraction pattern, typical of cereal starches and the relative degrees of crystallinity ranged from 9.62 to 15.50%. Differential scanning calorimetry (DSC) revealed that raw sorghum starch showed an endotherm with a peak temperature (Tp) at 78.06 °C and gelatinization enthalpies of 2.83 J/g whereas five-day malted sorghum starch had a Tp at 47.22 °C and gelatinization enthalpies of 2.06 J/g. Storage modulus (G') and loss modulus (G″) of all starch suspensions increased steeply to a maximum at 70 °C and then decreased with continuous heating. The structural analysis of malted sorghum starch showed porosity on the granule's surface susceptible to the amylolysis. The results showed that physicochemical and functional properties of sorghum starches are influenced by soaking and malting methods.
从浸泡和发芽的高粱中分离出淀粉,并对其进行研究以了解其物理化学性质和功能特性。在低于50°C的温度下,两种淀粉的膨胀力(SP)和水溶性指数(WSI)几乎相似,但在高于50°C时,从发芽高粱中分离出的淀粉比从未加工和浸泡高粱中分离出的淀粉表现出更低的SP和更高的WSI。通过快速粘度分析仪(RVA)测定的淀粉糊化特性表明,发芽高粱淀粉的粘度峰值(86 BU/RVU)低于未加工高粱淀粉(454 BU/RVU)。对于两种高粱,X射线衍射图均呈现出典型的谷物淀粉A型衍射模式,相对结晶度范围为9.62%至15.50%。差示扫描量热法(DSC)显示,未加工高粱淀粉在78.06°C出现吸热峰,糊化焓为2.83 J/g,而经过五天发芽的高粱淀粉的吸热峰温度(Tp)为47.22°C,糊化焓为2.06 J/g。所有淀粉悬浮液的储能模量(G')和损耗模量(G'')在70°C时急剧上升至最大值,然后随着持续加热而下降。发芽高粱淀粉的结构分析表明,颗粒表面存在易受淀粉酶解作用影响的松孔结构。结果表明,高粱淀粉 的物理化学性质和功能特性受浸泡和发芽方法的影响。