Tetrakis(μ-2-chloro-benzoato-κO:O')bis-[(4-vinyl-pyridine-κN)copper(II)].
作者信息
Zhao Juan
机构信息
College of Mechanical Engineering, Qingdao Technological University, Qingdao 266033, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 27;64(Pt 10):m1336. doi: 10.1107/S1600536808030766.
Abstract
The title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(7)H(7)N)(2)], consists of centrosymmetric dinuclear mol-ecules with a Cu⋯Cu separation of 2.6676 (12) Å. In the mol-ecule, four 2-chloro-benzoate anions bridge two Cu(II) ions, while two neutral 4-vinyl-pyridine ligands coordinate them in axial positions. The Cu(II) ion has a distorted square-planar pyramidal coordination, with four O atoms from the chlorobenzoate anions at the base. The N pyridine atom completes the coordination environment in the apical position.
摘要
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