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N,N'-双(3-甲氧基-亚苄基)乙烷-1,2-二胺

N,N'-Bis(3-methoxy-benzyl-idene)ethane-1,2-diamine.

作者信息

Fun Hoong-Kun, Mirkhani Valiollah, Vartooni Akbar Rostami

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 23;64(Pt 9):o1803-4. doi: 10.1107/S1600536808026652.

Abstract

The mol-ecule of the title bidentate Schiff base ligand, C(18)H(20)N(2)O(2), has twofold crystallographic rotation symmetry, giving one half-mol-ecule per asymmetric unit. It adopts a twisted E configuration with respect to the azomethine C=N bond. The imino group is coplanar with the aromatic ring. The dihedral angle between the two benzene rings is 69.52 (5)°. The meth-oxy group is coplanar with the benzene ring, as indicated by the C-O-C-C torsion angle of -179.56 (8)°. In the unit cell, mol-ecules are linked together by inter-molecular C-H⋯O hydrogen bonds, forming chains along the a axis; these chains are further stacked down the b axis by both inter-molecular C-H⋯O and C-H⋯π inter-actions.

摘要

标题为C(18)H(20)N(2)O(2)的双齿席夫碱配体分子具有二重晶体学旋转对称性,每个不对称单元中有半个分子。它相对于偶氮甲碱C=N键采取扭曲的E构型。亚氨基与芳环共面。两个苯环之间的二面角为69.52 (5)°。甲氧基与苯环共面,C-O-C-C扭转角为-179.56 (8)°表明了这一点。在晶胞中,分子通过分子间C-H⋯O氢键连接在一起,沿a轴形成链;这些链通过分子间C-H⋯O和C-H⋯π相互作用进一步沿b轴堆积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a7d4/2960703/60e32682dbe5/e-64-o1803-fig1.jpg

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