2,4,6-三氨基-1,3,5-三嗪-1,3-二铵水合五氟铝酸盐
2,4,6-Triamino-1,3,5-triazine-1,3-diium aqua-penta-fluoridoaluminate.
作者信息
Cadiau A, Hemon-Ribaud A, Leblanc M, Maisonneuve V
机构信息
Laboratoire des Oxydes et Fluorures - UMR 6010 CNRS, Faculté des Sciences et Techniques, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 5;64(Pt 4):m523-4. doi: 10.1107/S1600536808004091.
The title compound, (C(3)H(8)N(6))[AlF(5)(H(2)O)], was obtained by solvothermal synthesis from the reaction of aluminium hydroxide, 1,3,5-triazine-2,4,6-triamine (melamine), aqueous HF and water at 323 K for 48 h. The structure consists of AlF(5)(H(2)O) octa-hedra and diprotonated melaminium cations. Cohesion is ensured by a three-dimensional network of hydrogen bonds.
标题化合物（C₃H₈N₆）[AlF₅（H₂O）]是通过氢氧化铝、1,3,5-三嗪-2,4,6-三胺（三聚氰胺）、氢氟酸水溶液和水在323K下反应48小时，经溶剂热合成得到的。其结构由[AlF₅（H₂O）]²⁻八面体和双质子化的三聚氰胺阳离子组成。通过三维氢键网络确保了凝聚作用。
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