四（硫脲-κS）钯（II）硫氰酸盐
Tetrakis(thiourea-κS)palladium(II) dithio-cyanate.
作者信息
Nadeem Shafqat, Khawar Rauf M, Ebihara Masahiro, Tirmizi Syed Ahmed, Ahmad Saeed
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 23;64(Pt 5):m698-9. doi: 10.1107/S160053680801088X.
The title compound, Pd(CH(4)N(2)S)(4)(2), consists of complex Pd(TU)(4) [TU = thio-urea, SC(NH(2))(2)] cations and thio-cyanate counter-anions. The Pd(II) cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The complex cations are connected through the thio-cyanate ions via N-H⋯N [2.922 (3)-3.056 (3) Å] and N-H⋯S [3.369 (2)-3.645 (2) Å] hydrogen bonds.
标题化合物Pd(CH₄N₂S)₄₂由[Pd(TU)₄]²⁺络阳离子[TU = 硫脲，SC(NH₂)₂]和硫氰酸根抗衡阴离子组成。Pd(II)阳离子位于一个对称中心上，通过硫脲配体的S原子呈现出近似平面正方形的配位结构。络阳离子通过硫氰酸根离子经由N—H⋯N [2.922 (3) - 3.056 (3) Å]和N—H⋯S [3.369 (2) - 3.645 (2) Å]氢键相连。
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