Bis(μ-N-benzyl-N-methyl-dithio-carbamato)-1:2κS,S':S';1:2κS:S,S'-bis-[bis-(N-benzyl-N-methyl-dithio-carbamato-κS,S')thallium(III)].
作者信息
Rizzoli Corrado, Ramalingam Kuppukkannu, Alexander Nagarajan
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 12;64(Pt 8):m1020-1. doi: 10.1107/S1600536808021004.
Abstract
The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio-carbamate anions in a distorted penta-gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C-H⋯S hydrogen-bond inter-action linking complex mol-ecules into chains running parallel to the b axis. Intramolecular C-H⋯S hydrogen bonds are also present.
摘要
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