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采用简单且经济有效的溶胶-凝胶工艺制备的 SiO2 薄膜的光谱和电学性能。

Spectroscopic and electrical properties of SiO2 films prepared by simple and cost effective sol-gel process.

机构信息

Department of Physics, Government Science College, Bangalore 560001, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2011 Feb;78(2):695-9. doi: 10.1016/j.saa.2010.11.051. Epub 2010 Dec 8.

Abstract

Amorphous SiO2 thin films were prepared on glass and silicon substrates by cost effective sol-gel method. Tetra ethyl ortho silicate (TEOS) was used as the precursor material, ethanol as solvent and concentrated HCl as a catalyst. The films were characterized at different annealing temperatures. The optical transmittance was slightly increased with increase of annealing temperature. The refractive index was found to be 1.484 at 550 nm. The formation of SiO2 film was analyzed from FT-IR spectra. The MOS capacitors were designed using silicon (100) substrates. The current-voltage (I-V), capacitance-voltage (C-V) and dissipation-voltage (D-V) measurements were taken for all the annealed films deposited on Si (100). The variation of current density, resistivity and dielectric constant of SiO2 films with different annealing temperatures was investigated and discussed for its usage in applications like MOS capacitor. The results revealed the decrease of dielectric constant and increase of resistivity of SiO2 films with increasing annealing temperature.

摘要

采用经济有效的溶胶-凝胶法在玻璃和硅衬底上制备非晶态 SiO2 薄膜。正硅酸乙酯(TEOS)用作前体材料,乙醇用作溶剂,浓盐酸用作催化剂。在不同的退火温度下对薄膜进行了表征。随着退火温度的升高,光学透过率略有增加。在 550nm 处测得折射率为 1.484。通过傅里叶变换红外光谱(FT-IR)分析了 SiO2 薄膜的形成。使用硅(100)衬底设计 MOS 电容器。对所有在 Si(100)上沉积的退火薄膜进行了电流-电压(I-V)、电容-电压(C-V)和耗散电压(D-V)测量。研究并讨论了不同退火温度下 SiO2 薄膜的电流密度、电阻率和介电常数的变化,以将其应用于 MOS 电容器等领域。结果表明,随着退火温度的升高,SiO2 薄膜的介电常数降低,电阻率增大。

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