Han Peng-de, Zhang Le, Huang Xiao-gu, Wang Li-xi, Zhang Qi-tu
College of Materials Science and Engineering, Nanjing University of Technology, Nanjing 210009, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2010 Nov;30(11):2906-10.
Y2O3 powders doped with rare-earth ions were synthesized by sol-gel combustion synthesis. Effects of different calcinating temperatures, Er+ doping concentration and Yb3+ doping concentration were investigated. It was shown that the single well crystallized Y2O3 powders could be obtained at 800 degrees C; as the calcinating temperature increased, the crystallinity and upconversion luminescence intensity were higher; the particle size was uniform around 1 microm at 900 degrees C; when Er3+ doping concentration was 1 mol%, the green upconversion luminescence intensity reached the maximum, but for red upconversion luminescence, when Er3+ doping concentration was 4 mol%, its luminescence intensity reached the maximum; as the ratio of Yb3+ to Er3+ was 4:1, the green emission intensity reached the maximum, while the red emission intensity was always increasing as Yb3+ doping concentration increased.
采用溶胶-凝胶燃烧合成法制备了掺杂稀土离子的Y2O3粉末。研究了不同煅烧温度、Er+掺杂浓度和Yb3+掺杂浓度的影响。结果表明,在800℃可获得结晶良好的单一Y2O3粉末;随着煅烧温度升高,结晶度和上转换发光强度更高;在900℃时粒径均匀,约为1微米;当Er3+掺杂浓度为1mol%时,绿色上转换发光强度达到最大值,但对于红色上转换发光,当Er3+掺杂浓度为4mol%时,其发光强度达到最大值;当Yb3+与Er3+的比例为4:1时,绿色发射强度达到最大值,而红色发射强度则随着Yb3+掺杂浓度的增加而不断增加。