Federal Bureau of Investigation, Laboratory Division, 2501 Investigation Parkway, Quantico, VA 22135, United States.
Forensic Sci Int. 2011 Mar 20;206(1-3):161-5. doi: 10.1016/j.forsciint.2010.07.033. Epub 2011 Feb 4.
The chemistry of children's latent fingerprint residues was investigated as a function of time and temperature by non-destructive spectrochemical analysis. Latent fingerprints from children, ranging in age from 2 to 11 years, were deposited onto aluminum-coated glass slides and were analyzed by Fourier-Transform Infrared Microspectroscopy. The results revealed that there are three major classes of compounds present in children's latent fingerprints: carboxylic acid salts, proteins, and esters. By studying the changes in the fingerprint residues as a function of time and at elevated temperatures, we discovered that the salts in the fingerprint residues are stable relative to the esters. These findings have relevant forensic implications; by targeting the acid salts instead of the esters or proteins, children's latent fingerprints may be recovered after extended periods of time have elapsed.
通过非破坏性光谱化学分析研究了儿童潜在指纹残留物的化学成分随时间和温度的变化。将年龄在 2 至 11 岁之间的儿童潜在指纹沉积在涂有铝的玻璃幻灯片上,并通过傅里叶变换红外微光谱法进行分析。结果表明,儿童潜在指纹中存在三类主要化合物:羧酸盐、蛋白质和酯类。通过研究指纹残留物随时间和升高温度的变化,我们发现指纹残留物中的盐相对于酯类更为稳定。这些发现具有相关的法医学意义;通过针对酸盐而不是酯类或蛋白质,可以在经过很长一段时间后恢复儿童的潜在指纹。