通过优先手性溶剂化作用洞察超分子堆积中的手性诱导。
Insight into the chiral induction in supramolecular stacks through preferential chiral solvation.
机构信息
Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands.
出版信息
Chem Commun (Camb). 2011 Mar 28;47(12):3451-3. doi: 10.1039/c0cc04617e. Epub 2011 Feb 7.
PMID:21298189
Abstract
Preferred handedness in the supramolecular chirality of self-assembled achiral oligo(p-phenylenevinylene) (OPV) derivatives is induced by chiral solvents and spectroscopic probing provides insight into the mechanistic aspects of this chiral induction through chiral solvation.
摘要
手性溶剂诱导自组装非手性寡聚对苯乙炔（OPV）衍生物的超分子手性偏好，光谱探测通过手性溶剂化深入了解这种手性诱导的机制方面。
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