Department of Chemical and Environmental Engineering, Bourns College of Engineering, Riverside, CA 92521, USA.
J Air Waste Manag Assoc. 2011 Jan;61(1):14-21. doi: 10.3155/1047-3289.61.1.14.
Large auxiliary engines operated on ocean-going vessels in transit and at berth impact the air quality of populated areas near ports. This paper presents new information on the comparison of emission ranges from three similar engines and the effectiveness of three control technologies: switching to cleaner burning fuels, operating in the low oxides of nitrogen (NOx) mode, and selective catalytic reduction (SCR). In-use measurements of gaseous (NOx, carbon monoxide [CO], carbon dioxide [CO2]) and fine particulate matter (PM2.5; total and speciated) emissions were made on three auxiliary engines on post-PanaMax class container vessels following the International Organization for Standardization-8178-1 protocol. The in-use NOx emissions for the MAN B&W 7L32/40 engine family vary from 15 to 21.1 g/kW-hr for heavy fuel oil and 8.9 to 19.6 g/kW-hr for marine distillate oil. Use of cleaner burning fuels resulted in NOx reductions ranging from 7 to 41% across different engines and a PM2.5 reduction of up to 83%. The NOx reductions are a consequence of fuel nitrogen content and engine operation; the PM2.5 reduction is attributed to the large reductions in the hydrated sulfate and organic carbon (OC) fractions. As expected, operating in the low-NOx mode reduced NOx emissions by approximately 32% and nearly doubled elemental carbon (EC) emissions. However, PM2.5 emission factors were nearly unchanged because the EC emission factor is only approximately 5% of the total PM2.5 mass. SCR reduced the NOx emission factor to less than 2.4 g/kW-hr, but it increased the PM2.5 emissions by a factor of 1.5-3.8. This increase was a direct consequence of the conversion of sulfur dioxide to sulfate emissions on the SCR catalyst. The EC and OC fractions of PM2.5 reduced across the SCR unit.
在运输中和停泊时,远洋船舶上的大型辅助发动机对港口附近人口稠密地区的空气质量产生影响。本文提供了关于三种类似发动机的排放范围比较的新信息,以及三种控制技术的有效性:改用更清洁的燃烧燃料、在低氮氧化物(NOx)模式下运行,以及选择性催化还原(SCR)。按照国际标准化组织 8178-1 协议,在巴拿马型集装箱船舶之后,对三种辅助发动机进行了使用中气态(NOx、一氧化碳[CO]、二氧化碳[CO2])和细颗粒物(PM2.5;总含量和特定物质)排放的测量。曼恩 B&W 7L32/40 发动机系列的在用 NOx 排放量因重燃料油而异,范围为 15 至 21.1 g/kW-hr,而船用馏分油则为 8.9 至 19.6 g/kW-hr。使用更清洁的燃烧燃料可使不同发动机的 NOx 减排量达到 7%至 41%,并使 PM2.5 减排量达到 83%。NOx 的减少是燃料含氮量和发动机运行的结果;PM2.5 的减少归因于水合硫酸盐和有机碳(OC)分数的大量减少。正如预期的那样,在低 NOx 模式下运行可将 NOx 排放量减少约 32%,并使元素碳(EC)排放量增加近一倍。然而,PM2.5 排放因子几乎不变,因为 EC 排放因子仅占 PM2.5 总质量的约 5%。SCR 将 NOx 排放因子降低至低于 2.4 g/kW-hr,但将 PM2.5 排放量增加了 1.5-3.8 倍。这一增加是 SCR 催化剂上二氧化硫转化为硫酸盐排放的直接后果。SCR 装置使 PM2.5 中的 EC 和 OC 分数减少。