钯(0)催化炔丙酯的[1,5]-σ迁移重排反应生成取代萘胺。
Pd(0)-catalyzed [1,5]-sigmatropic hydrogen shift of propargylic esters toward substituent naphthylamines.
机构信息
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P.R. China.
出版信息
J Org Chem. 2011 Mar 18;76(6):1941-4. doi: 10.1021/jo1024267. Epub 2011 Feb 11.
PMID:21314095
Abstract
A novel and convenient carboannulation method for the synthesis of highly substituted naphthylamine derivatives has been developed though a Pd(0)-catalyzed [1,5]-sigmatropic hydrogen shift and cyclization reaction of propargyl esters.
摘要
发展了一种新颖且方便的碳环化方法，通过钯（0）催化的炔丙酯[1,5]-σ迁移重排和环化反应，用于合成高取代萘基胺衍生物。
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