Instituto de Física Gleb Wataghin, Universidade Estadual de Campinas-UNICAMP, Campinas, SP, Brazil.
J Phys Condens Matter. 2010 Dec 8;22(48):486002. doi: 10.1088/0953-8984/22/48/486002. Epub 2010 Nov 12.
Magnetocaloric properties of antiferromagnetic RGa(2) (R = Ce, Pr, Nd, Dy, Ho and Er) compounds have been reported. These systems present an antiferromagnetic transition below 15 K and a field induced metamagnetic transition from the antiferromagnetic to ferromagnetic state. Our results show that the character of the magnetic field induced transition along the series affects the magnetocaloric properties. For the compounds with R = Ho, Dy and Er both negative and positive magnetocaloric effect (MCE) were observed above μ(0)ΔH = 2 T where the rate between negative and positive MCE contributions depends on how the magnetic transitions occur in these compounds. The evaluated values of maximum magnetocaloric properties of RGa(2) compounds are similar to other potential magnetic refrigerant materials reported in the literature.
反铁磁 RGax(R = Ce、Pr、Nd、Dy、Ho 和 Er)化合物的磁热性能已经被报道。这些体系在 15 K 以下呈现反铁磁转变,并在磁场诱导下从反铁磁态转变为铁磁态。我们的结果表明,沿该系列的磁场诱导转变的特性影响磁热性能。对于 R = Ho、Dy 和 Er 的化合物,在 μ(0)ΔH = 2 T 以上观察到了正、负磁热效应(MCE),其中正负 MCE 贡献之间的比率取决于这些化合物中磁转变的发生方式。所评估的 RGax 化合物的最大磁热性能值与文献中报道的其他潜在磁性制冷剂材料相似。