Ghosh S, Nayek P, Roy S K, Gangopadhyay R, Rahaman Molla M, Majumder T P
Department of Spectroscopy, Indian Association for the Cultivation of Science, Kolkata, India.
Eur Phys J E Soft Matter. 2011 Apr;34(4):35. doi: 10.1140/epje/i2011-11035-6. Epub 2011 Apr 8.
A detailed comparative study of the dielectric and electro-optical properties of a ferroelectric liquid crystal (FLC) and FLC after having doped with conducting polymer Poly (3,4-ethylenedioxythiophene) (PEDOT) nanotubes is done. The electro-optic study reveals a lower electrical response time, rotational viscosity and spontaneous polarization in the FLC/PEDOT nanocomposite system. By fitting the capacitance with voltage in a Preisach model, four dipolar species in both FLC and composites system have been obtained. The orientation of the four dipolar species in the composites system is such that the effective dipole moment in the transverse direction of the FLC molecule is less than that in FLC compound.
对铁电液晶(FLC)以及掺杂了导电聚合物聚(3,4 - 乙撑二氧噻吩)(PEDOT)纳米管后的FLC的介电和电光特性进行了详细的对比研究。电光研究表明,FLC/PEDOT纳米复合体系具有更低的电响应时间、旋转粘度和自发极化。通过在Preisach模型中将电容与电压进行拟合,在FLC和复合体系中均获得了四种偶极子种类。复合体系中四种偶极子种类的取向使得FLC分子横向方向上的有效偶极矩小于FLC化合物中的有效偶极矩。