相转移催化下酚盐促进的亚胺的三氟甲基化反应。一种用于硅烷对亚胺加成反应的通用催化平台。
Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines.
机构信息
Department of Organic Chemistry A. Mangini, University of Bologna, V. Risorgimento 4, 40136 Bologna, Italy. luca.bernardi2@.unibo.it
出版信息
Chem Commun (Camb). 2012 Feb 1;48(10):1428-30. doi: 10.1039/c0cc05777k. Epub 2011 Apr 11.
PMID:21479321
Abstract
A new approach to additions of silicon nucleophiles to imines was developed. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions.
摘要
发展了一种向亚胺加成硅亲核试剂的新方法。该方法基于铵催化剂的酚盐相转移，克服了酰胺加合物促进反应的能力不足。
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