The mechanism of sonophotocatalytic degradation of methyl orange and its products in aqueous solutions.

In this study, it was found that a hybrid technique, sonophotocatalysis, is able to degrade a parent organic pollutant (methyl orange) as well as its by-products. The analysis of products formed during the whole degradation has demonstrated that the pH or the selection of oxidation process (sonolysis/photocatalysis/sonophotocatalysis) is able to control the degradation pathway. It was shown in the by-products analysis that the solution pH can alter the amount of each product generated during the sonophotocatalytic degradation. It was revealed that the different degradation rates of methyl orange and its products result from the solution pH and the nature of the organic products. Furthermore, a comparison of the data obtained from the oxidation processes on the degradation of the reaction intermediates identified the advantages of the combined system. It is concluded that sonophotocatalysis is capable of yielding a more complete and faster mineralization of organic pollutants than the individual processes. However, as in the degradation of the parent compound, the overall mineralization is lower than an additive effect (negative synergistic effect).