Ordered Matter Science Research Center, Southeast University, Nanjing 211189, PR China.
Chem Soc Rev. 2011 Jul;40(7):3577-98. doi: 10.1039/c0cs00226g. Epub 2011 Apr 20.
Ferroelectric materials are of importance and interest in both fundamental scientific research and various technological applications. Metal-organic complexes (MOCs) represent a class of molecule-based ferroelectrics, which have shown various properties or functionalities due to their hybrid inorganic-organic nature. This tutorial review shows the recent development of the MOC ferroelectrics with particular emphases on the mechanism of ferroelectric-to-paraelectric phase transition, symmetry consideration, and multifunctionality.
铁电材料在基础科学研究和各种技术应用中都具有重要意义和兴趣。金属-有机配合物(MOC)代表了一类基于分子的铁电体,由于其混合无机-有机性质,它们表现出各种性质或功能。本综述展示了 MOC 铁电体的最新发展,特别强调了铁电-顺电相转变的机制、对称性考虑和多功能性。