界面的主客体化学用于光致开关生物电化学

Host-guest chemistry at interface for photoswitchable bioelectrocatalysis.

机构信息

Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Haidian District, Beijing 100084, China.

出版信息

Chem Commun (Camb). 2011 Jun 7;47(21):5994-6. doi: 10.1039/c1cc11289a. Epub 2011 Apr 21.

DOI:10.1039/c1cc11289a

PMID:21509391

Abstract

Photoswitchable bioelectrocatalysis of glucose with glucose oxidase in an "On-Off" state is fabricated from host-guest chemistry at an interface by using the photocontrolled reversible immobilization and detachment of ferrocene-labeled redox-polymer as mediator.

摘要

通过光控可逆固定和脱附二茂铁标记的氧化还原聚合物作为介体，在界面上利用主体-客体化学构建了处于“开-关”状态的葡萄糖氧化酶的光开关型生物电化学。