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双[2-(4-羟基苯基)乙酸根合-κO]双(1,10-菲咯啉-κN,N')镉五水合物

Bis[2-(4-hy-droxy-phen-yl)acetato-κO]bis-(1,10-phenanthroline-κN,N')cadmium penta-hydrate.

作者信息

Yu Yu-Ye

机构信息

Jinhua College of Vocation and Technology, Jinhua, Zhejiang 321017, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m246. doi: 10.1107/S1600536811001747.

Abstract

In the title compound, [Cd(C(8)H(7)O(3))(2)(C(12)H(8)N(2))(2)]·5H(2)O, the Cd(II) ion is six-coordinated by two carboxylate O atoms of monodentate 2-(4-hy-droxy-phen-yl)acetate ligands and by four N atoms from two chelating 1,10-phenantroline ligands in a distorted trigonal-prismatic geometry. O-H⋯O hydrogen bonds between water mol-ecules and the complex mol-ecules result in the formation of a three-dimensional network. Four water mol-ecules act as single acceptors and double donors while the fifth water mol-ecule is involved as a single acceptor and single donor in an O-H⋯O inter-action and as a donor in an O-H⋯π inter-action.

摘要

在标题化合物[Cd(C₈H₇O₃)₂(C₁₂H₈N₂)₂]·5H₂O中,Cd(II)离子由单齿2-(4-羟基苯基)乙酸酯配体的两个羧酸根O原子以及来自两个螯合的1,10-菲啰啉配体的四个N原子以扭曲的三角棱柱几何构型进行六配位。水分子与配合物分子之间的O-H⋯O氢键导致形成三维网络。四个水分子充当单受体和双供体,而第五个水分子作为单受体和单供体参与O-H⋯O相互作用,并作为供体参与O-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7ab1/3051641/7b84dfc5f58c/e-67-0m246-fig1.jpg

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