Bis(ferrocenecarbaldehyde 4-methyl-thio-semicarbazonato-κN,S)zinc(II) methanol solvate.
作者信息
Vikneswaran M R, Teoh Siang Guan, Quah Ching Kheng, Fun Hoong-Kun
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 8;65(Pt 9):m1027. doi: 10.1107/S1600536809030086.
Abstract
In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(8)H(9)N(3)S)(2)]·CH(3)OH, the dihedral angles between the substituted and unsubstituted cyclo-penta-dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn(II) atom at the flap. Each methanol solvent mol-ecule is linked to three ferrocene groups via inter-molecular O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds. The crystal structure is further consolidated by C-H⋯π inter-actions.
摘要
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