Murtaza Ghulam, Ebihara Masahiro, Said Muhammad, Khawar Rauf M, Anwar Saeed
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 29;65(Pt 9):o2297-8. doi: 10.1107/S160053680903387X.
In the title compound, C(20)H(15)Cl(2)N(3)O, a typical polysubstituted guanidine with normal geometric parameters, the torsion angles [C-N-C-O = 3.8 (2), N-C-N-C = -6.1 (2)°] indicate that the guanidine and carbonyl groups are almost coplanar, due to the pseudo-hexa-gonal ring formed by intra-molecular N-H⋯O hydrogen bonds. The crystal packing is stabilized by inter-molecular N-H⋯O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers.
在标题化合物C₂₀H₁₅Cl₂N₃O中,这是一个具有正常几何参数的典型多取代胍,扭转角[C-N-C-O = 3.8 (2),N-C-N-C = -6.1 (2)°]表明,由于分子内N-H⋯O氢键形成的准六边形环,胍基和羰基几乎共面。晶体堆积通过分子间N-H⋯O氢键得以稳定,这些氢键将分子连接成中心对称的二聚体。