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2-苯甲酰基-1-(2,4-二氯苯基)-3-苯基胍

2-Benzoyl-1-(2,4-dichloro-phen-yl)-3-phenyl-guanidine.

作者信息

Murtaza Ghulam, Ebihara Masahiro, Said Muhammad, Khawar Rauf M, Anwar Saeed

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 29;65(Pt 9):o2297-8. doi: 10.1107/S160053680903387X.

Abstract

In the title compound, C(20)H(15)Cl(2)N(3)O, a typical polysubstituted guanidine with normal geometric parameters, the torsion angles [C-N-C-O = 3.8 (2), N-C-N-C = -6.1 (2)°] indicate that the guanidine and carbonyl groups are almost coplanar, due to the pseudo-hexa-gonal ring formed by intra-molecular N-H⋯O hydrogen bonds. The crystal packing is stabilized by inter-molecular N-H⋯O hydrogen bonds, which link the mol-ecules into centrosymmetric dimers.

摘要

在标题化合物C₂₀H₁₅Cl₂N₃O中,这是一个具有正常几何参数的典型多取代胍,扭转角[C-N-C-O = 3.8 (2),N-C-N-C = -6.1 (2)°]表明,由于分子内N-H⋯O氢键形成的准六边形环,胍基和羰基几乎共面。晶体堆积通过分子间N-H⋯O氢键得以稳定,这些氢键将分子连接成中心对称的二聚体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7188/2970011/175996f7b4ae/e-65-o2297-fig1.jpg

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