Khan Islam Ullah, Sahin Onur, Jillani Shehzada Muhammad Sajid, Sharif Shahzad, Büyükgüngör Orhan
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 30;66(Pt 5):m587-8. doi: 10.1107/S1600536810015072.
In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octa-hedral coordination environment. The two benzothia-zole-2-thiol-ate ligands chelate via their thia-zole N and thiol-ate S atoms while the methyl 2-(2-amino-thia-zol-4-yl)-2-(methoxy-imino)acetate also acts as a chelate ligand binding through the thia-zole and imino N atoms. Intra-molecular N-H⋯N, C-H⋯N and C-H⋯O inter-actions contribute to the mol-ecular conformation. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds produce R(1) (2)(6) rings and generate chains along the c axis. An extensive one-dimensional supra-molecular network of N-H⋯O hydrogen bonds and C-H⋯π inter-actions is responsible for the crystal structure stabilization.
在标题化合物[Ni(C₇H₄NS₂)₂(C₇H₉N₃O₃S)]中，Ni(II)离子处于略微扭曲的N₄S₂八面体配位环境中。两个苯并噻唑-2-硫醇盐配体通过其噻唑N和硫醇盐S原子螯合，而2-(2-氨基噻唑-4-基)-2-(甲氧基亚氨基)乙酸甲酯也作为螯合配体，通过噻唑和亚氨基N原子结合。分子内的N-H⋯N、C-H⋯N和C-H⋯O相互作用有助于分子构象。在晶体结构中，分子间的N-H⋯O氢键形成R(1)(2)(6)环，并沿c轴生成链。由N-H⋯O氢键和C-H⋯π相互作用构成的广泛的一维超分子网络负责晶体结构的稳定。
