Dolzhenko Anna V, Dolzhenko Anton V, Tan Geok Kheng, Koh Lip Lin, Pastorin Giorgia
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 30;66(Pt 5):o1209-10. doi: 10.1107/S1600536810015357.
In the title compound, C(7)H(12)N(6)O·2H(2)O, the Z configuration of the hydrazone fragment is stabilized by an intra-molecular N-H⋯N hydrogen bond involving one of the amino groups. In the crystal structure, the hydrazonamide mol-ecules are connected via inter-molecular N-H⋯O=C hydrogen bonds, forming C(7) chains running along [010]. The chains form sheets parallel to the (01). The chains are cross-linked by water mol-ecules to form a three-dimensional hydrogen-bonded network.
在标题化合物C₇H₁₂N₆O·2H₂O中,腙片段的Z构型通过涉及其中一个氨基的分子内N-H⋯N氢键得以稳定。在晶体结构中,腙酰胺分子通过分子间N-H⋯O=C氢键相连,形成沿[010]方向延伸的C₇链。这些链形成平行于(01)的片层。链通过水分子交联形成三维氢键网络。