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[二(2,6 - 二异丙基苯基)戊烷 - 2,4 - 二胺 -(1 -)- 2κN,N'] - μ(2)- 氯 - 1:2κCl:Cl - 氯 - 2κCl - 双 -(1,2 - 二甲氧基乙烷 - 1κO,O')铁(II)锂

[N,N'-Bis(2,6-diisopropyl-phen-yl)pentane-2,4-diamine-(1-)-2κN,N']-μ(2)-chlorido-1:2κCl:Cl-chlorido-2κCl-bis-(1,2-di-methoxy-ethane-1κO,O')iron(II)lithium.

作者信息

Grubba Rafał, Ponikiewski Lukasz, Tomorowicz Lukasz, Pikies Jerzy

机构信息

Chemical Faculty, Gdansk University of Technology, Narutowicza 11/12, Gdansk PL-80233, Poland.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 May 26;66(Pt 6):m707. doi: 10.1107/S1600536810018222.

Abstract

In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra-hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy-ethane mol-ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034 Å.

摘要

在标题化合物[FeLi(C₂₉H₄₁N₂)Cl₂(C₄H₁₀O₂)₂]中,Fe(II)原子由两个N原子和两个Cl原子配位,形成扭曲的FeN₂Cl₂四面体几何构型。此外,其中一个氯原子桥连到一个锂离子上,该锂离子被两个二甲氧基乙烷分子溶剂化,并处于扭曲的三角双锥环境中配位。中心的Fe、Cl(×2)和Li原子共面,最大偏差为0.034 Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/73c9/2979477/2c803fee9907/e-66-0m707-fig1.jpg

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