1,8 - 双（对甲苯磺酰氧基）- 9,10 - 蒽醌
1,8-Bis(tos-yloxy)-9,10-anthraquinone.
作者信息
Niedziałkowski Paweł, Trzybiński Damian, Sikorski Artur, Ossowski Tadeusz
机构信息
Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 4;66(Pt 1):o33-4. doi: 10.1107/S1600536809051009.
Abstract
In the crystal structure of the title compound, C(28)H(20)O(8)S(2), adjacent anthracene skeletons are parallel or inclined at an angle of 20.6 (1)°. In the mol-ecular structure, the mean plane of the anthracene skeleton makes dihedral angles of 49.6 (1) and 76.8 (1)° with the tosyl rings, and the two terminal benzene rings are oriented at an angle of 74.5 (1)° with respect to each other. The crystal structure is stabilized by inter-molecular C-H⋯O and C-O⋯π inter-actions.
摘要
在标题化合物C(28)H(20)O(8)S(2)的晶体结构中，相邻的蒽骨架相互平行或呈20.6 (1)°的倾斜角。在分子结构中，蒽骨架的平均平面与对甲苯磺酰环的二面角为49.6 (1)°和76.8 (1)°，且两个末端苯环彼此间的取向角度为74.5 (1)°。晶体结构通过分子间的C-H⋯O和C-O⋯π相互作用得以稳定。
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