Abu-Safieh Kayed A, Khanfar Monther A, Eichele Klaus, Ali Basem Fares
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 13;64(Pt 12):o2305. doi: 10.1107/S1600536808035964.
The asymmetric unit of the title compound, C(21)H(18)ClN(3)O(2)S, contains two mol-ecules in which the bond lengths and angles are almost identical. Intra-molecular N-H⋯S hydrogen bonds result in the formation of two five-membered rings. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers; these dimers are linked via inter-molecular O-H⋯S hydrogen bonds, leading to infinite corrugated layers parallel to the bc plane through R(2) (2)(16) ring motifs.
标题化合物C(21)H(18)ClN(3)O(2)S的不对称单元包含两个分子,其中键长和键角几乎相同。分子内N-H⋯S氢键导致形成两个五元环。在晶体结构中,分子间N-H⋯O氢键将分子连接成中心对称的二聚体;这些二聚体通过分子间O-H⋯S氢键相连,通过R(2) (2)(16)环 motif形成平行于bc平面的无限波纹层。