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4-（4-氯苯基）-1-（2-羟基-2,2-二苯基乙酰基）硫代氨基脲

4-(4-Chloro-phen-yl)-1-(2-hydr-oxy-2,2-di-phenyl-acet-yl)thio-semicarbazide.

作者信息

Abu-Safieh Kayed A, Khanfar Monther A, Eichele Klaus, Ali Basem Fares

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 13;64(Pt 12):o2305. doi: 10.1107/S1600536808035964.

DOI:10.1107/S1600536808035964
PMID:21581282
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2959801/
Abstract

The asymmetric unit of the title compound, C(21)H(18)ClN(3)O(2)S, contains two mol-ecules in which the bond lengths and angles are almost identical. Intra-molecular N-H⋯S hydrogen bonds result in the formation of two five-membered rings. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers; these dimers are linked via inter-molecular O-H⋯S hydrogen bonds, leading to infinite corrugated layers parallel to the bc plane through R(2) (2)(16) ring motifs.

摘要

标题化合物C(21)H(18)ClN(3)O(2)S的不对称单元包含两个分子，其中键长和键角几乎相同。分子内N-H⋯S氢键导致形成两个五元环。在晶体结构中，分子间N-H⋯O氢键将分子连接成中心对称的二聚体；这些二聚体通过分子间O-H⋯S氢键相连，通过R(2) (2)(16)环 motif形成平行于bc平面的无限波纹层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4189/2959801/2a8e2030790f/e-64-o2305-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4189/2959801/c406c42f39ce/e-64-o2305-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4189/2959801/bb9e3672e6a4/e-64-o2305-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4189/2959801/2a8e2030790f/e-64-o2305-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4189/2959801/c406c42f39ce/e-64-o2305-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4189/2959801/bb9e3672e6a4/e-64-o2305-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4189/2959801/2a8e2030790f/e-64-o2305-fig3.jpg

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