Shi Hao, Sun Hong Xiang
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 24;65(Pt 1):o202. doi: 10.1107/S1600536808043341.
The title compound, C(24)H(32)O(8)S·C(3)H(6)O, features three six-membered and two five-membered rings. The six-membered rings adopt chair, boat and slightly distorted boat conformations whereas one five-membered ring adopts an approximate envelope conformation and the other a twist conformation. Disorder was modelled for the ethyl-thio group with the ethyl-C atoms resolved over three positions with occupancies of 0.58 (4), 0.23 (4) and 0.19 (3). In the crystal, an O-H⋯O hydrogen bond links the molecules into chains.
标题化合物C(24)H(32)O(8)S·C(3)H(6)O具有三个六元环和两个五元环。六元环呈现椅式、船式和轻微扭曲的船式构象,而一个五元环采用近似信封式构象,另一个采用扭转构象。乙硫基存在无序,乙基碳原子在三个位置解析,占有率分别为0.58 (4)、0.23 (4)和0.19 (3)。在晶体中,O—H⋯O氢键将分子连接成链。