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Poly[aqua-bis(μ-benzene-1,2-dicarboxyl-ato)ethano-ltetra-lithium].

作者信息

Rodríguez-Cuamatzi Patricia, Tlahuext Hugo, Höpfl Herbert

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 4;65(Pt 3):m246. doi: 10.1107/S1600536809003390.

Abstract

In the crystal structure of the title compound Li(4)(C(8)H(4)O(4))(2)(C(2)H(5)OH)(H(2)O), there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxyl-ate groups act as bidentate-bridging ligands producing a two-dimensional coordination network parallel to the ab plane. The coordination polymer is further stabilized by coordination of water and ethanol mol-ecules by the Li(+) ions. Simultaneously, the water and ethanol mol-ecules are involved in O-H⋯O and C-H⋯π inter-actions.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2466/2968522/e62486d8a82c/e-65-0m246-fig1.jpg

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