聚[[三-μ-氰基-氰基(1,4,10,13-四氧杂-7,16-二氮杂环十八烷)钡(II)铂(II)]]半水合物
Poly[[tri-μ-cyanido-cyanido(1,4,10,13-tetra-oxa-7,16-diaza-cyclo-octa-deca-ne)barium(II)platinum(II)] hemihydrate].
作者信息
Olmstead Marilyn M, Beavers Christine M, Paw U Latisha
机构信息
Department of Chemistry, University of California, Davis, CA 95616, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 19;65(Pt 4):m408-9. doi: 10.1107/S1600536809008915.
The title compound, {[BaPt(CN)(4)(C(12)H(26)N(2)O(4))]·0.5H(2)O}(n), is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the (01) set of crystal planes. In the crystal structure, disordered water mol-ecules (half occupancy) connect the sheets into a three-dimensional network via inter-molecular O-H⋯O hydrogen bonds. An N-H⋯N inter-action is also present. The shortest Pt⋯Pt contacts are 7.5969 (4) Å by an inversion relationship and 7.6781 (4) Å by translation along the a axis.
标题化合物{[BaPt(CN)₄(C₁₂H₂₆N₂O₄)]·0.5H₂O}ₙ是一种二维配位聚合物，其中这些片层大致平行于(01)晶面组取向。在晶体结构中，无序水分子（占据率为一半）通过分子间O—H⋯O氢键将这些片层连接成三维网络。还存在N—H⋯N相互作用。通过反演关系，最短的Pt⋯Pt接触距离为7.5969 (4) Å，沿a轴平移时为7.6781 (4) Å。
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