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Bis(3-hydroxy-pyridine-κN)bis-(3-nitro-benzoato-κO)zinc(II).

作者信息

Li Jun-Hua, Nie Jing-Jing, Xu Duan-Jun

机构信息

Department of Chemistry, Zhejiang University, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 15;65(Pt 8):m927. doi: 10.1107/S1600536809027147.

Abstract

The title complex, [Zn(C(7)H(4)NO(4))(2)(C(5)H(5)NO)(2)], has site symmetry 2. The Zn(II) ion is located on a crystallographic twofold rotation axis and assumes a distorted tetra-hedral ZnN(2)O(2) coordination geometry. Mol-ecules are linked by an inter-molecular O-H⋯O hydrogen bond and π-π stacking inter-actions between pyridine rings [centroid-centroid speparation 3.594 (1) Å].

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa3/2977432/9e817efa54a7/e-65-0m927-fig1.jpg

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本文引用的文献

1
Poly[(μ-3,5-dinitro-2-oxidobenzoato)(μ-3-hydroxy-pyridine)copper(II)].
Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 10;64(Pt 5):m651-2. doi: 10.1107/S1600536808009392.
2
A short history of SHELX.
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Intramolecular pi-pi stacking in diaquabis(2-hydroxybenzoato-kappaO)bis(1,10-phenanthroline-kappa2N,N')strontium(II).
Acta Crystallogr C. 2007 Dec;63(Pt 12):m622-4. doi: 10.1107/S0108270107050597. Epub 2007 Nov 30.

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