4-{[(5-甲基-2-呋喃基)亚甲基]肼羰基}吡啶氯化物一水合物
4-{[(5-Methyl-2-fur-yl)methyl-ene]hydrazinocarbon-yl}pyridinium chloride monohydrate.
作者信息
Li Li-Min, Jian Fang-Fang, Liu Li
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 25;65(Pt 8):o1983. doi: 10.1107/S1600536809028426.
Abstract
The title compound, C(12)H(12)N(3)O(2) (+)·Cl(-)·H(2)O, was prepared by the reaction of N'-[(5-methyl-2-fur-yl)methyl-ene]isonicotino-hydrazide and hydro-chloric acid at room temperature. The entire molecule is approximately planar with a maximum deviation of 0.047 (2) Å. An intramolecular C-H⋯O interaction is observed. O-H⋯Cl, N-H⋯Cl, N-H⋯O, N-H⋯N, C-H⋯Cl and C-H⋯O hydrogen-bonds stabilize the crystal structure.
摘要
标题化合物C(12)H(12)N(3)O(2) (+)·Cl(-)·H(2)O是通过N'-[(5-甲基-2-呋喃基)亚甲基]异烟酰肼与盐酸在室温下反应制备的。整个分子近似平面结构，最大偏差为0.047 (2) Å。观察到分子内存在C-H⋯O相互作用。O-H⋯Cl、N-H⋯Cl、N-H⋯O、N-H⋯N、C-H⋯Cl和C-H⋯O氢键稳定了晶体结构。
Zotero 插件